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Atomistry » Oxygen » Chemical Properties » Flame Uniform Propagation » Law of Speeds » Vertical Propagation of Flame » |
Slow Uniform Propagation of Flame
In 1882 Mallard and Le Chatelier gave the results of an investigation into the rate of propagation of flame in mixtures of air and a combustible
Upper and Lower Flash-Points
gas such as hydrogen and methane. It was observed that if the combustible mixture was ignited at the closed end of a horizontal tube, open to the air at the other end, the flame tended to travel with increasing velocity towards the open end. In a detonating mixture of hydrogen and air a speed of 300 metres per second was registered. If, on the other hand, the combustible mixture was ignited at the open end, the flame was observed to travel for a short distance at a uniform speed. This was followed by a vibratory movement, in the course of which the flame travelled backwards and forwards in an irregular manner, the mean speed from point to point along the tube being usually greater than that of the uniform movement. These vibrations usually continued to the end of the tube, but sometimes, during a particularly violent vibration, the flame might be extinguished, owing to contamination of the as yet unburnt mixture with the products of combustion. The initial slow propagation of flame can be maintained at a uniform speed over a considerable distance of travel from the point of ignition with all combustible mixtures of gases under ordinary conditions of temperature and pressure, provided suitable precautions are taken. The conditions most favourable to obtain and maintain this uniform movement are that the inflammable mixture should be contained in a long, straight, and horizontal tube open at one end and closed at the other; and that ignition should be effected at the open end of the tube by a source of heat not greatly exceeding in temperature the ignition- temperature of the mixture, and not productive of mechanical disturbance of the mixture. The speed of the uniform movement then depends on the composition of the mixture and on the diameter of the containing tube. Above a certain (small) diameter the material of which the tube is made does not appreciably affect the speed of the flame. With a tube of given diameter the speed of the uniform movement of flame in a mixture may - according to Mason and Wheeler - be regarded as a definite physical constant for that mixture.
For the examination of flames, such as those of mixtures of methane and air, which are non-actinic, various devices have been employed. A useful one used by Wheeler consisted in filling a horizontal tube with the gaseous mixture, the ends of the tube being closed, as shown in fig., by flanged end-pieces, bearing taps. S1, S2, S3 . . . were screen wires of copper, 0.025 mm. in diameter, threaded vertically across the tube through fine holes pierced through the walls. In order to avoid including in the measurements of the speed of the flame any impetus that might be given by the igniting spark, the first screen-wire was fixed 40 cm. from the point of ignition. Other screen- wires were fixed 50, 100, 200, 300, and 400 cm. respectively from the first. The method of recording the time of passage of flame along the tube was electrical. Each screen-wire carried a small electric current, the interruption of this current when the flame melted the wires being recorded by the movement of an electro-magnet. The electric current passing through the screen-wires was sufficient to raise them nearly to red heat. This arrangement ensured the rapid melting of the wires as soon as the flame touched them, and therefore gave very uniform results; wires made from metals or alloys of low melting-point, which could not be drawn so fine or of so uniform a diameter as copper, were found to be unsatisfactory. All electrical connections through the screen-wires and chronograph having been established, the left-hand end-piece of the explosion-tube was removed (by sliding it downwards) and the mixture ignited at the now open end by passing an induction-coil spark at A.
When, however, the diameter is increased above 10 cm., the speed of the flames is affected by the coming into play of another factor, namely, convection. This is noticeable with the fastest moving flames in tubes 10 cm. in diameter, the visible effect being a turbulence of the flame front. This is essentially a swirling motion in a direction nearly normal to the direction of translation of the flame front, which, as in tubes of smaller diameter, progresses at a uniform speed for about 150 cm. before backward and forward vibrations are set up. This swirling motion appears ab initio, and is due to rapid movement of the hot gases from below upwards by convection. In tubes of comparatively small diameter (5 to 9 cm.) this rapid movement is suppressed.
If the diameter of the tube is sufficiently small,|the flame dies out after travelling a short distance. Still further reduction in the diameter of the tube renders it impossible for the flame to spread from the point of ignition. This was discovered by Davy, and constituted the starting- point of his researches 011 the construction of his well-known safety lamp for use in coal mines. He found that in tubes 1/7-inch in diameter (i.e. 3.63 mm.) explosive mixtures of firedamp and air could not be fired as no flame would pass along. Analogous results were obtained by Mallard and Le Chatelier, who found the speeds of flame in a mixture of methane and air containing 10.4 per cent, of methane, using tubes of glass of different diameters, to be as follow:
Consideration of the curves shown in fig. shows that the flame-speeds of mixtures of methane and ail steadily rise to maximum values as the percentage of the combustible gas is raised from its lower limit of 5.6 to about 10 per cent. Further addition of methane reduces the speed until the flame is extinguished just beyond the upper limit value. This was to be anticipated for, beyond a certain value, excess of the combustible gas will usually function as a diluent. The shape of the curve, therefore, is typical.
The author points out that the most striking results are those for mixtures of methane with pure oxygen. The speed is then 5500 cm. per second - more than fifty times that attained in air. It will be further observed that the maximum speed of the flame is obtained with the mixture in which the methane and oxygen are present in combining proportions, namely, CH4 + 2O2. This result is in noteworthy distinction to that obtaining when the detonation-wave is developed in mixtures of methane and oxygen, for the mixture in which the speed of the detonation-wave is greatest contains equal proportions of methane and oxygen. The difference is the more striking when it is remembered that the uniform movement may give place to the detonation-wave after quite a short distance of travel of the flame. The flame-speeds of combustible mixtures of hydrogen and air are less easy to determine since the flame travels more rapidly and in some mixtures the explosion-wave may be set up after the flame has travelled but a short distance (about 2 metres) from the end of the tube.
The higher and lower limit speeds tend to approach the same value of 20 cm. per second for all the gases. It is interesting to note that in every case, except that of methane, the maximum flame speed occurs with a mixture containing more of the combustible gas than is required for complete combustion.
In the following table are given the maximum uniform flame speeds of various combustible mixtures, together with the flame speeds at approximately the upper and lower limits in horizontal tubes of diameter 2.5 cm. |
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